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1.
Pigment & Resin Technology ; 52(4):490-501, 2023.
Article in English | ProQuest Central | ID: covidwho-20242763

ABSTRACT

PurposeThis study aims to focus on the preparation and characterization of the silver nanowire (AgNWs), as well as their application as antimicrobial and antivirus activities either with incorporation on the waterborne coating formulation or on their own.Design/methodology/approachPrepared AgNWs are characterized by different analytical instruments, such as ultraviolet-visible spectroscope, scanning electron microscope and X-ray diffraction spectrometer. All the paint formulation's physical and mechanical qualities were tested using American Society for Testing and Materials, a worldwide standard test procedure. The biological activities of the prepared AgNWs and the waterborne coating based on AgNWs were investigated. And, their effects on pathogenic bacteria, antioxidants, antiviral activity and cytotoxicity were also investigated.FindingsThe obtained results of the physical and mechanical characteristics of the paint formulation demonstrated the formulations' greatest performance, as well as giving good scrub resistance and film durability. In the antimicrobial activity, the paint did not have any activity against bacterial pathogen, whereas the AgNWs and AgNWs with paint have similar activity against bacterial pathogen with inhibition zone range from 10 to 14 mm. The development of antioxidant and cytotoxicity activity of the paint incorporated with AgNWs were also observed. The cytopathic effects of herpes simplex virus type 1 (HSV-1) were reduced in all three investigated modes of action when compared to the positive control group (HSV-1-infected cells), suggesting that these compounds have promising antiviral activity against a wide range of viruses, including DNA and RNA viruses.Originality/valueThe new waterborne coating based on nanoparticles has the potential to be promising in the manufacturing and development of paints, allowing them to function to prevent the spread of microbial infection, which is exactly what the world requires at this time.

2.
Bulletin of Engineering Geology and the Environment ; 81(8), 2022.
Article in English | CAB Abstracts | ID: covidwho-20235953

ABSTRACT

The rapid response to the COVID-19 pandemic has resulted in increased municipal waste in the form of used face masks (FMs), which pose a global threat to the environment. To mitigate this, the study explores the applicability of shredded FMs as alternative reinforcing material in sands. Laboratory-grade Ottawa sand and naturally collected sea sand are adopted as the base sands for testing. The primary physical properties of the base materials and the FMs are first examined, and the soil particles are imaged via scanning electron microscopy. Thirty consolidated undrained (CU) triaxial compression tests were conducted to evaluate the effects of the weight fraction of FM, FM length, and the initial effective mean stress on the undrained shear strength parameters of the sands. The experimental results proved that FM inclusion can lead to a substantial improvement in the undrained shear strength of the sands;however, such improvement was sensitive to the initial effective mean stress, with higher undrained shear strength gains associated with lower initial effective mean stress. For a given FM content, the critical state ratio and angle of friction at the critical state increased with the FM length. Finally, the results revealed that FM-reinforced sands exhibit dilative and strain-hardening behaviors.

3.
Polymers (Basel) ; 15(11)2023 May 31.
Article in English | MEDLINE | ID: covidwho-20243692

ABSTRACT

There is an ever-growing interest in recovering and recycling waste materials due to their hazardous nature to the environment and human health. Recently, especially since the beginning of the COVID-19 pandemic, disposable medical face masks have been a major source of pollution, hence the rise in studies being conducted on how to recover and recycle this waste. At the same time, fly ash, an aluminosilicate waste, is being repurposed in various studies. The general approach to recycling these materials is to process and transform them into novel composites with potential applications in various industries. This work aims to investigate the properties of composites based on silico-aluminous industrial waste (ashes) and recycled polypropylene from disposable medical face masks and to create usefulness for these materials. Polypropylene/ash composites were prepared through melt processing methods, and samples were analyzed to get a general overview of the properties of these composites. Results showed that the polypropylene recycled from face masks used together with silico-aluminous ash can be processed through industrial melt processing methods and that the addition of only 5 wt% ash with a particle size of less than 90 µm, increases the thermal stability and the stiffness of the polypropylene matrix while maintaining its mechanical strength. Further investigations are needed to find specific applications in some industrial fields.

4.
Int J Adv Manuf Technol ; 126(11-12): 4963-4982, 2023.
Article in English | MEDLINE | ID: covidwho-20234888

ABSTRACT

The aim of this paper is to study the mechanical behavior of corrugated board boxes, focusing attention on the strength that the boxes are able to offer in compression under stacking conditions. A preliminary design of the corrugated cardboard structures starting from the definition of each individual layer, namely the outer liners and the innermost flute, was carried out. For this purpose, three distinct types of corrugated board structures that include flutes with different characteristics, namely the high wave (C), the medium wave (B), and even the micro-wave (E), were comparatively evaluated. More specifically, the comparison is able to show the potential of the micro-wave which would eventually allow a significant saving of cellulose in the fabrication process of the boxes, thus reducing the manufacturing costs and causing a lower environmental footprint. First, experimental tests were carried out to determine the mechanical properties of the different layers of the corrugated board structures. Tensile tests were performed on samples extracted from the paper reels used as base material for the manufacturing of the liners and flutes. Instead, the edge crush test (ECT) and box compression test (BCT) were directly performed on the corrugated cardboard structures. Secondly, a parametric finite element (FE) model to allow, on a comparative basis, the study of the mechanical response of the three different types of corrugated cardboard structures was developed. Lastly, a comparison between the available experimental results and the outputs of the FE model was carried out, with the same model being also adapted to evaluate additional structures where the E micro-wave was usefully combined with the B or C wave in a double-wave configuration.

5.
Solid Earth ; 14(5):529-549, 2023.
Article in English | ProQuest Central | ID: covidwho-2322957

ABSTRACT

The sediments underneath Mexico City have unique mechanical properties that give rise to strong site effects. We investigated temporal changes in the seismic velocity at strong-motion and broadband seismic stations throughout Mexico City, including sites with different geologic characteristics ranging from city center locations situated on lacustrine clay to hillside locations on volcanic bedrock. We used autocorrelations of urban seismic noise, enhanced by waveform clustering, to extract subtle seismic velocity changes by coda wave interferometry. We observed and modeled seasonal, co- and post-seismic changes, as well as a long-term linear trend in seismic velocity. Seasonal variations can be explained by self-consistent models of thermoelastic and poroelastic changes in the subsurface shear wave velocity. Overall, sites on lacustrine clay-rich sediments appear to be more sensitive to seasonal surface temperature changes, whereas sites on alluvial and volcaniclastic sediments and on bedrock are sensitive to precipitation. The 2017 Mw 7.1 Puebla and 2020 Mw 7.4 Oaxaca earthquakes both caused a clear drop in seismic velocity, followed by a time-logarithmic recovery that may still be ongoing for the 2017 event at several sites or that may remain incomplete. The slope of the linear trend in seismic velocity is correlated with the downward vertical displacement of the ground measured by interferometric synthetic aperture radar, suggesting a causative relationship and supporting earlier studies on changes in the resonance frequency of sites in the Mexico City basin due to groundwater extraction. Our findings show how sensitively shallow seismic velocity and, in consequence, site effects react to environmental, tectonic and anthropogenic processes. They also demonstrate that urban strong-motion stations provide useful data for coda wave monitoring given sufficiently high-amplitude urban seismic noise.

6.
Materials (Basel) ; 16(9)2023 Apr 26.
Article in English | MEDLINE | ID: covidwho-2318501

ABSTRACT

Professionals in industries are making progress in creating predictive techniques for evaluating critical characteristics and reactions of engineered materials. The objective of this investigation is to determine the optimal settings for a 3D printer made of acrylonitrile butadiene styrene (ABS) in terms of its conflicting responses (flexural strength (FS), tensile strength (TS), average surface roughness (Ra), print time (T), and energy consumption (E)). Layer thickness (LT), printing speed (PS), and infill density (ID) are all quantifiable characteristics that were chosen. For the experimental methods of the prediction models, twenty samples were created using a full central composite design (CCD). The models were verified by proving that the experimental results were consistent with the predictions using validation trial tests, and the significance of the performance parameters was confirmed using analysis of variance (ANOVA). The most crucial element in obtaining the desired Ra and T was LT, whereas ID was the most crucial in attaining the desired mechanical characteristics. Numerical multi-objective optimization was used to achieve the following parameters: LT = 0.27 mm, ID = 84 percent, and PS = 51.1 mm/s; FS = 58.01 MPa; TS = 35.8 MPa; lowest Ra = 8.01 m; lowest T = 58 min; and E = 0.21 kwh. Manufacturers and practitioners may profit from using the produced numerically optimized model to forecast the necessary surface quality for different aspects before undertaking trials.

7.
Acs Applied Nano Materials ; 6(3):1828-1838, 2023.
Article in English | Web of Science | ID: covidwho-2309571

ABSTRACT

The increasing emergence of infectious diseases like COVID-19 has created an urgent need for filtration/purification materials coupled with multifunctional features such as mechanical integrity, excellent airflow/filtration, and antibacterial/antimicrobial properties. Polymer membranes and metal-organic frameworks (MOFs) have demonstrated high effectiveness in air filtration and purification. MOF nanoparticles have been introduced into electrospun polymer nanofibrous membranes through embedding or postsolution growth. However, the derived hybrids are still facing the issue of (1) limited MOF exposure, which leads to low efficacy;and (2) uncontrollable growth, which leads to pore blocking and low breathability. In this work, we customized an electrospray-on-electrospinning in situ process to dynamically integrate MOF nanoparticles into a robust and elastic continuous nanofibrous membrane for advanced properties including high mechanical strength and flexibility, excellent breathability, particle filtration, and good antimicrobial performance. Biodegradable polylactic acid was reinforced by the poly(hydroxybutyrate)-di-poly(DLA-CL)x copolymer (PHBR) and used as an electrospinning matrix, while MOF nanoparticles were simultaneously electrically sprayed onto the nanofibers with easily controllable MOF loading. The MOF nanoparticles were homogeneously deposited onto nanofibers without clogging the pores in the membrane. The collision of PLA and MOF under the wet status during electrospinning and the hydrogen bonding through C=O and N-H bonds strengthen the affinity between PLA nanofibers and MOF nanoparticles. Because of these factors, the MOF-incorporated PLA/PHBR nanofibrous membrane achieved over 95% particle filtration efficiency with enhanced mechanical properties while maintaining high breathability. Meanwhile, it exhibits excellent photocatalytic antibacterial performance, which is necessary to kill microbes. The electrospray-on-electrospinning in situ process provides an efficient and straightforward way to hybridize one-dimensional (1D) or two-dimensional (2D) nanomaterials into a continuous nanofibrous membrane with strong interaction and controllable loading. Upon integrating proper functionalities from the materials, the obtained hybrids are able to achieve multifunctionalities for various applications.

8.
Cailiao Daobao/Materials Reports ; 37(6), 2023.
Article in Chinese | Scopus | ID: covidwho-2298743

ABSTRACT

R apid, sensitive and specific detection of viruses is a key issue in the medical field. Since 2020, the global outbreak of COVID-19 requires more sensitive virus detection methods. With the development of new materials, especially nanomaterials, many materials have demonstrated great physical, chemical and mechanical properties, which present potential for virus detection. Nanomaterials can be divided into zero-dimensional materials, one-dimensional materials and two-dimensional materials by structure. In this paper, the classification and the latest progress of nanomaterials are reviewed, highlighting their applications in the field of virus detection. The future prospect of nanomaterials in virus detection is also presented and discussed. © 2023 Cailiao Daobaoshe/ Materials Review. All rights reserved.

9.
Minerals ; 13(4):505, 2023.
Article in English | ProQuest Central | ID: covidwho-2294950

ABSTRACT

Stoneware is a ceramic material with low porosity and high mechanical properties, such as the modulus of rupture. It is essentially made of clay, feldspar and quartz and is sintered to create a mixture of glass and crystalline phases. With the projected growth rate of the global ceramics market size and the country's development plan for 2023–2028, it is imperative that alternative raw materials for the manufacture of ceramic products be sourced so that the importation of these materials, such as feldspar, be minimized, if not eliminated. Cinder in the Philippines is mainly used as a filling material in pavements and residential areas. In this study, this resource is utilized as partial and full replacement of feldspar in a typical ternary diagram for stoneware production. Bars were formed from different formulations by the slip casting method and were sintered at 1200 °C. Physical and mechanical properties of the bars, such as shrinkage, loss on ignition, water absorption, apparent porosity and modulus of rupture were determined. Thermo-physical analyses were also carried out on the raw materials and on formulated powders. Meeting the requirements of the various quality standards for ceramics, the partial replacement of feldspar with black cinder (LF, LFBQ and LFBH) is feasible for wall and roof applications while full replacement of feldspar with black cinder (LB) is suitable for wider use as wall, floor, vitrified, industrial and roof tiles.

10.
Buildings ; 13(4):919, 2023.
Article in English | ProQuest Central | ID: covidwho-2294825

ABSTRACT

Plastic waste causes severe environmental impacts worldwide and threatens the lives of all creatures. In the medical field, most of the equipment, especially personal protective equipment (PPE), is made from single-use plastic. During COVID-19, the usage of PPE has increased, and is disposed of in landfills after being used once. Worldwide, millions of tons of waste syringes are generated from COVID-19 vaccination. A practical alternative to utilizing this waste is recycling it to reinforce building materials. This research introduces an approach to using COVID-19 syringe plastic waste to reinforce building material as composite concrete. Reinforced fiber polymer (FRP) concrete materials were used to mold cylindrical specimens, which underwent mechanical tests for mechanical properties. This study used four compositions with 0%, 5%, 10%, and 15% of FRP to create cylindrical samples for optimum results. Sequential mechanical tests were carried out on the created samples. These specimens were cured for a long period to obtain water absorption capability. After several investigations, the highest tensile and compressive strengths, approximately 2.0 MPa and 10.5 MPa, were found for the 5% FRP composition samples. From the curing test, the lowest water absorbability of around 5% was found for the 5% FRP composition samples.

11.
Journal of Marine Science and Engineering ; 11(4):851, 2023.
Article in English | ProQuest Central | ID: covidwho-2293981

ABSTRACT

Fibre-reinforced plastic (FRP) materials are attracting growing interest because of their high specific mechanical properties. These characteristics, in addition to a high level of tailorability and design of freedom, make them attractive for marine, aerospace, automotive, sports and energy applications. However, the large use of this class of material dramatically increases the amount of waste that derives from end-of-life products and offcuts generated during the manufacturing processes. In this context, especially when thermosetting matrices are considered, the need to deeply study the recycling process of FRPs is an open topic both in academic and industrial research. This review aims to present the current state of the art of the most affirmed recycling technologies used for polymeric composites commonly used in industrial applications, such as carbon and glass FRPs. Each recycling method (i.e., chemical, thermal and mechanical) was analysed in terms of technological solutions and process parameters required for matrix dissolution and fibre recovery, showing their advantages, drawbacks, applications and properties of the recycled composites. Therefore, the aim of this review is to offer an extensive overview of the recycling process of polymeric composite materials, which is useful to academic and industrial researchers that work on this topic.

12.
J Vet Med Sci ; 85(3): 386-392, 2023 Mar 28.
Article in English | MEDLINE | ID: covidwho-2297856

ABSTRACT

Investigating the characteristics of tracheas can help the understanding of diseases related to the trachea, particularly tracheal collapse (TC) in dogs. This study aimed to compare the mechanical properties of tracheas from New Zealand White (NZW) rabbits and dogs and to introduce a method for inducing a model of TC in the normal trachea. Tracheal samples were obtained from NZW rabbit cadavers (n=5) weighing 3.62-3.92 kg and from dog cadavers (n=5) weighing 2.97-3.28 kg. Three live NZW rabbits weighing 3.5-4.0 kg were used to establish the model. The radial forces of both sample sets were measured using a digital force gauge and statistically compared. Subsequently, TC was surgically induced in three female NZW rabbits by physically weakening their tracheal cartilage under general anesthesia. Their clinical signs were monitored for 3 months, and radiographic examinations were performed monthly for 3 months. The mean radial forces of the two sample sets were comparable (P>0.05). The clinical signs, radiographic examinations, and macroscopic examinations were all comparable to those of dogs with TC. The cadaveric study between the rabbits and dogs demonstrated that the surgically induced rabbit model of TC is an excellent candidate for the experimental study of dogs with TC. This study also provides a reference of tracheal radial force values to enable selection of appropriate mesh types and wire diameters of self-expanding metal stents.


Subject(s)
Dog Diseases , Rabbits , Female , Animals , Dogs , Dog Diseases/surgery , Trachea/surgery , Metals , Stents/veterinary , Prosthesis Implantation/veterinary
13.
Journal of Structural Fire Engineering ; 14(1):61-89, 2023.
Article in English | ProQuest Central | ID: covidwho-2260534

ABSTRACT

PurposeIn the present article, the authors have conducted a review on some of the recent developments given in the literature pertaining to the passive protection of concrete structures using intumescent coatings. Here, the main thrust is placed on the spalling phenomenon of concrete elements when exposed to elevated temperatures and fires.Design/methodology/approachIn this context, it has been long established that prolonged thermal insult on concrete members will lead to egress of water, both physically bound as well as those present as water of hydration within the concrete matrix, in the form of steam through microchannels and associated pathways of least resistance, often resulting in the flaking of the surface of the structure. The latter process can ultimately lead to the exposure of the ferrous-based reenforcement elements, for instance, to higher temperatures, thus inducing melting. This, in turn, can result in substantial loss of strength and load-bearing capacity of the structural element that is already undergoing disintegration of its base matrix owing to heat/fire. Even though spalling of concrete structures has long been recognized as a serious problem that can often lead to catastrophic failure of infrastructures, such as buildings, bridges and tunnels, the utility of intumescent coating as a mitigation strategy is relatively new and has not been explored to its fullest possible extent. Therefore, in the latter parts of the review, the authors have endeavored to discuss the different types of intumescent coatings, their modes of actions and, in particular, their wider applicability in terms of protecting concrete elements from detrimental effects of severe or explosive spalling.FindingsGiven that spalling of concrete components is still a very serious issue that can result in loss of lives and destruction of critical infrastructures, there is an urgent need to formulate better mitigating strategies, through novel means and methods. The use of the intumescent coating in this context appears to be a promising way forward but is one that seems to be little explored so far. Therefore, a more systematic investigation is highly warranted in this area, especially, as the authors envisage a greater activity in the building and commissioning of more infrastructures worldwide incommensurate with augmented economic activities during the post-COVID recovery period.Originality/valueThe authors have conducted a review on some of the recent developments given in the literature pertaining to the passive protection of concrete structures using intumescent coatings. The authors have also included the results from some recent tests carried out at the facilities using a newly commissioned state-of-the-art furnace.

14.
IOP Conference Series Materials Science and Engineering ; 1275(1):011001, 2023.
Article in English | ProQuest Central | ID: covidwho-2259773

ABSTRACT

The Italian Association for Stress Analysis (AIAS) was founded in 1971 by researchers from academia, research centers, and industry. AIAS was intended as a community where to discuss, share, and develop scientific knowledge related to all technical aspects of stress analysis. In the years, from an initial focus on experimental techniques, AIAS contributed considerably to the development of modern numerical methods and computational techniques for mechanical engineering design. In 2015, AIAS turned in the Italian Scientific Society of Mechanical Engineering Design.Today, AIAS is an institutional partner that supports the instances from academia in the subject area of mechanical engineering design. Every year, AIAS organizes a technical conference offering the possibility to present research updates, share new ideas, and foster collaborations. The AIAS conference has become a fundamental event for all those interested in current developments in mechanical engineering design and stress analysis, where to meet researchers, testing equipment, and software developers.The 51st AIAS Conference edition was held in Padova, Italy again in presence after two years of online-only events due to the COVID-19 pandemic.The response of researchers and students has been outstanding: over 200 oral contributions have been presented during the three days of the conference, with four parallel sessions. In addition to the thematic sessions on AIAS traditional subjects, special sessions on additive manufacturing, energy methods for structural analysis, circular design in mechanical engineering, and mechanical behavior under extreme conditions, have been successfully organized with the contribution of the AIAS technical committees.Among all contributions presented at the conference, 48 have been selected to be published after peer review, in this volume. This was made possible thanks to the active participation of all AIAS members, to the work of the AIAS Scientific Committee and Conference Papers Review panel (Profs Giovanni Meneghetti, AIAS Scientific Coordinator, Luciano Afferrante, Francesco Bucchi, Filippo Cianetti, Enrico Armentani, Marco Sasso). Their outstanding contribution is gratefully acknowledged.DisclaimerAIAS2022 Conference was held in presence on Sept. 7-10, 2022. Presentations were arranged in four parallel sessions with a time slot of 15 min assigned to each presenter. Approximately 250 participants attended the conference during the three days event. All sessions have been continuously monitored by the organizers to provide technical support. The conference ran smoothly, and the participants' feedback was very positive.

15.
Sustainability (Switzerland) ; 15(5), 2023.
Article in English | Scopus | ID: covidwho-2263390

ABSTRACT

Since 2020, with the global spread of major respiratory infectious diseases, such as COVID–19, the demand and consumption of personal protective equipment, such as masks, have increased dramatically worldwide. The environmental pollution caused by numerous waste disposable face masks has gradually attracted people's attention. In this study, the mechanical properties of mask–chip–reinforced soil are evaluated from a new perspective, through the uniaxial, biaxial, conventional triaxial, and true triaxial compression tests on reshaped sandy soil samples mixed with different contents of mask chips. The experimental results show that the mechanical properties of the sandy soil can be improved by the mask chips. With the proper content of mask chips, the failure strength is substantially improved, and the failure of soil is delayed. Meanwhile, the strength and stiffness are significantly affected by the stress path and the content of mask chips, even if the soil samples with the same mask–chip content can also show different mechanical properties under different stress paths. Additionally, the mechanical properties of soil are not necessarily improved constantly with the increasing content of mask chips. The failure strength of sandy soil samples under conventional and true triaxial stress paths decreases when the mass content of mask chips exceeds 0.3% and 0.5%, respectively. This study confirms the potential of mask chips applied to subgrade, slope, and other engineering construction fields in a sustainable way. © 2023 by the authors.

16.
Chem Phys ; 569: 111859, 2023 May 01.
Article in English | MEDLINE | ID: covidwho-2271420

ABSTRACT

SARS-CoV-2-encoded accessory protein ORF3a was found to be a conserved coronavirus protein that shows crucial roles in apoptosis in cells as well as in virus release and replications. To complete the knowledge and identify the unknown of this protein, further comprehensive research is needed to clarify the leading role of ORF3a in the functioning of the coronavirus. One of the efficient approaches to determining the functionality of this protein is to investigate the mechanical properties and study its structural dynamics in the presence of physical stimuli. Herein, performing all-atom steered molecular dynamics (SMD) simulations, the mechanical properties of the force-bearing components of the ORF3a channel are calculated in different physiological conditions. As variations occurring in ORF3a may lead to alteration in protein structure and function, the G49V mutation was also simulated to clarify the relationship between the mechanical properties and chemical stability of the protein by comparing the behavior of the wild-type and mutant Orf3a. From a physiological conditions point of view, it was observed that in the solvated system, the presence of water molecules reduces Young's modulus of TM1 by ∼30 %. Our results also show that by substitution of Gly49 with valine, Young's modulus of the whole helix increases from 1.61 ± 0.20 to 2.08 ± 0.15 GPa, which is consistent with the calculated difference in free energy of wild-type and mutant helices. In addition to finding a way to fight against Covid-19 disease, understanding the mechanical behavior of these biological nanochannels can lead to the development of the potential applications of the ORF3a protein channel, such as tunable nanovalves in smart drug delivery systems, nanofilters in the new generation of desalination systems, and promising applications in DNA sequencing.

17.
Composites Communications ; 37, 2023.
Article in English | Scopus | ID: covidwho-2246435

ABSTRACT

The hazards of epoxy resin (EP) are not only reflected in the large amount of smoke and heat released during combustion, but also in the long survival time of bacterial on their surfaces at a time when COVID-19 are prevalent. Therefore, it is crucial to improve the antibacterial properties and fire-resistance of EP. Herein, this paper reports a multifunctional nanoparticle (Cu2O@KF) to overcome this issue. It is found that Cu2O@KF can confer great fire-resistance (LOI = 34.7% and pHRR reduced by 56.3%), antibacterial properties (over 99.99% antibacterial efficiency), and mechanical properties (hardness and Young's modulus increased by 80.0% and 24.0%, respectively) at a low loading level (7 wt%). These ideal characteristics are derived from the multi-synergistic properties among Cu2O and KF. © 2022

18.
Journal of the Textile Institute ; 114(1):55-65, 2023.
Article in English | Scopus | ID: covidwho-2241397

ABSTRACT

With the emergence of the COVID-19, masks and protective clothing have been used in huge quantities. A large number of non-degradable materials have severely damaged the ecological environment. Now, people are increasingly pursuing the use of environmentally friendly materials to replace traditional chemical materials. Silk fibroin (SF) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) have received increasing attention because of their unique biodegradability and biocompatibility. In this paper, a series of biodegradable SF/PHBV nanofiber membranes with different PHBV content were fabricated by using electrospinning technology. The morphology of the electrospun SF/PHBV composite nanofiber was observed by scanning electron microscopy (SEM). The average diameters of the pure SF, SF/PHBV (4/1), SF/PHBV (3/1), and SF/PHBV (2/1) nanofibers were 55.16 ± 12.38 nm, 75.93 ± 21.83 nm, 69.35 ± 21.55 nm, and 61.40 ± 12.31 nm, respectively. Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) were used to explore the microstructure of the electrospun SF/PHBV composite nanofiber. The crystallization ability of the composite nanofiber was greatly improved with the addition of PHBV. The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) indicated that the thermal stability of SF was better than PHBV obviously, so SF could improve the thermal stability of the composite materials within a certain range. The mechanical properties of the electrospun nanofiber membranes were evaluated by using a universal testing machine. In general, the elongation of the composite nanofiber membranes decreased, and the breaking strength increased with the addition of PHBV. The small pore size of the nanofiber membranes ensured that they had good application prospects in the field of filtration and protection. When the spinning time was 1 h, the filtration efficiency of SF/PHBV/PLA composite materials remained above 95%. © 2021 The Textile Institute.

19.
Constr Build Mater ; 344: 128245, 2022 Aug 15.
Article in English | MEDLINE | ID: covidwho-2227143

ABSTRACT

Global public response to the COVID-19 (SARS-CoV-2) pandemic is highly focused on human health. However, conservationists have cautioned of unprecedented threats to the natural environment from a new type of non-biodegradable microplastic waste resulting from extensive use of disposable medical face masks (DMFMs). Thus, this waste must be recycled in an eco-friendly manner on an urgent basis. In this research, we developed a new environmentally friendly recycling technique using waste DMFMs in sustainable green concrete. More explicitly, a new fiber hybridization approach has been introduced in which two types of fibers namely DMFM fiber and basalt fiber (BF) were incorporated into fiber reinforced recycled aggregate concrete (FRAC). The volume fractions of DMFM fiber were 0%, 0.1%, and 0.2% and the volume fractions of BF were 0%, 0.25%, and 0.5%. In addition, two mineral admixtures (fly ash and ground granulated blast furnace slag) were also used. Test results indicated increase of approximately 12% in compressive strength, 26% in split tensile strength, and 60% in flexural strength of FRAC containing hybrid fibers and mineral admixtures. The density and ultra-sonic pulse velocity (UPV) of DMFM fiber- and BF-modified FRAC ranged from 2406-2433 kg/m3 and 4502-4541 m/s, respectively, which meets structural concrete requirements. The water absorption rate gradually increased with an increase in the volume fractions of fibers but remained within the allowable water absorption limit for construction materials. Lastly, the microstructure investigation indicated excellent concrete quality, improved interfacial transition zones (ITZs), and good compatibility of host concrete matrix with both DMFM fiber and BF that correlates well with the experimental results reported in this study.

20.
BioResources ; 17(2):3718-3780, 2022.
Article in English | ProQuest Central | ID: covidwho-2226306

ABSTRACT

The increasing usage of petroleum-based compounds has prompted numerous environmental concerns. Consequently, there has been a steady rise in research on the synthesis of useful materials from natural sources. Paper technologists are seeking environmentally acceptable dry end and wet end additives. Among the bio-based resources available, nanocellulose is a popular sustainable nanomaterial additive in the paper industry because of its high strength, high oxygen barrier performance, low density, great mechanical properties, and biocompatibility. NC's extensive hydroxyl groups provide a unique possibility to dramatically modify the hydrophilicity and charge of the surface in order to improve their potential applications in the paper industry. The current paper reviews two series of surface modifications, each with various subcategories, depending on why modified nanocellulose is added in the paper production: to improve barrier properties or to improve mechanical properties of packaging materials. The methods presented in this study use the minimum amount of chemically hazardous solvents to have the least impact on the environment. This review focuses on modifications of nanocellulose and their subsequent application in the papermaking. The knowledge and the discussion presented in this review will form a literature source for future use by various stakeholders and the sustainable paper manufacturers.

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